پایان نامه مدل سازی ریاضی پیل های سوختی میکروبیولوژیکی با هدف تولید انرژی و تصفیه فاضلاب

فهرست:

چکیده

1

مقدمه

2

فصل اول : درآمدی بر پیل سوختی میکروبیولوژیکی

3

 مفاهیم

4

 مروری بر واسط های حمل الکترون در MFC ها

7

 میکروب هایی که در پیل های سوختی میکروبی کاربرد دارند

8

پیکربندی پیل های سوختی میکروبی

12

اجزای MFC

12

سیستمهای MFC دو جزئی

13

سیستمهای MFC تک جزئی

16

1-4-4)      سیستمهای MFC نوع Up-flow

19

1-4-5)      پیل سوختی میکروبی انباشته (stacked)

21

عملکرد MFC ها

22

1-5-1) عملکرد ایده آل

22

1-5-2) بازدهی واقعی MFC

24

1-5-3) تاثیر شرایط عملیاتی

26

1-5-4) تاثیر جنس الکترودها

27

1-5-5) بافر pH و الکترولیت

29

1-5-6) سیستم مبادله پروتون

30

1-5-7) شرایط عملیاتی در محفظه آند

31

1-5-8) شرایط عملیاتی در محفظه کاتد

32

کاربردها

34

1-6-1) تولید الکتریسیته

34

1-6-2) بیوهیدروژن (Biohydrogen)

36

1-6-3) تصفیه فاضلاب

37

1-6-4) سنسورهای بیولوژیکی (Biosensors)

38

چشم انداز MFC ها

39

فصل دوم : مباحث فنی پیل های سوختی

41

2-1) ولتاژ پیل و پتانسیل الکترود ها

42

2-2) وابستگی ولتاژ پیل تعادلی به غلظت: معادله عمومی Nernst

44

2-3) پتانسیل های فلز/یون فلزی (+M/Mz)

46

2-4) پتانسیل های اکسایش/کاهش (RED/OX)

48

2-5) کاربرد معادله Nernst در وابستگی پتانسیل RedOx به غلظت

50

2-6) محاسبه پتانسیل های تعادلی الکترود

51

2-7) الکترود هیدروژن

52

2-8) الکترودهای فلز/نمک نامحلول/یون

54

2-9) الکترود کالومل

56

2-10) الکترود نقره/کلرید نقره

57

2-11) الکترود جیوه-سولفات جیوه

59

2-12) پتانسیل الکترود های استاندارد

60

2-13) غلظت و فعالیت

62

2-14) تئوری ضریب فعالیت Debye-Hückel: مدل نقطه-بار

63

2-15) تئوری ضریب فعالیت Debye-Hückel: مدل اندازه محدود یون

65

2-16) تصحیح Stokes-Robinson تئوری Debye-Hückel تاثیر اثر متقابل یون-حلال

66

فصل سوم : مدلسازی ریاضی پیل سوختی میکروبیوژیکی

68

3-1) ساختار کلی MFC مورد نظر برای مدلسازی

69

3-2) توسعه مدل

69

3-3) سرعت واکنش ها

71

3-4) حل مسئله

78

3-5) محاسبه پارامترها

78

3-6) بحث و نتیجه گیری

83

فصل چهارم : نتیجه گیری و پیشنهادات

84

فهرست مطالب

عنوان مطالب

شماره صفحه

منابع و ماخذ

86

فهرست منابع فارسی

86

فهرست منابع لاتین

87

سایت های اطلاع رسانی

97

چکیده انگلیسی

98

منبع:

فهرست منابع فارسی

مختاریان نادر، رحیم نژاد مصطفی، نجف پور قاسم، قریشی سیدعلی اصغر، تعیین میکرو ارگانیسم ها و همچنین محیط های کشت مناسب جهت استفاده در پیل های سوختی میکروبیولوژیکی به عنوان منبع پاک انرژی، ششمین همایش ملی بیوتکنولوژیکی جمهوری اسلامی ایران، مرداد 1388

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