فهرست:
فصل اول: مقدمه
1-1- پیشگفتار .....................................................................................................................................
1-2- معرفی کادمیوم .........................................................................................................................
1-2-1- خواص فیزیکی کادمیوم .....................................................................................................
1-2-2- کاربردهای کادمیوم .............................................................................................................
1-2-3- منابع آلودهکننده آب ..........................................................................................................
1-2-4- مواجهه انسان با آلودگی کادمیوم ............................................................................
1-2-5- اثرات کادمیوم بر روی سلامتی ........................................................................................
1-3- کربنات کلسیم ...........................................................................................................................
1-3-1- شکلهای کریستالی کربنات کلسیم ...............................................................................
1-4- کریستالیزاسیون ........................................................................................................................
1-4-1- فوق اشباعیت .......................................................................................................................
1-4-2- مکانیسم تشکیل بلور ..........................................................................................................
1-4-3- مکانیسم رشد بلور ...............................................................................................................
1-4-4- عوامل تجربی تعیین کننده اندازه ذرات .........................................................................
1-4-5- اثر اختلاط بر فرایند تبلور .................................................................................................
1-4-6- ترسیب ...................................................................................................................................
1-4-7- صاف کردن و شستشوی رسوب ......................................................................................
فصل دوم: مروری بر تحقیقات گذشته
عنوان
2-1- پیشگفتار .....................................................................................................................................
2-2- تکنیکهای حذف کادمیوم .....................................................................................................
2-2-1- روشهای شیمیایی .............................................................................................................
2-2-2- همرسوبی ..............................................................................................................................
2-2-3- تکنیک جداسازی غشا ........................................................................................................
2-2-4- تکنیک تبادل یونی .............................................................................................................
2-2-5- تکنیک استخراج با حلال ...................................................................................................
2-2-6- تکنیک جذب ........................................................................................................................
2-3- نتایج ............................................................................................................................................
فصل سوم: آزمایشگاهی
3-1- شرح دستگاه آزمایش ..............................................................................................................
3-2- روش تهیه محلولهای آزمایش .............................................................................................
3-3- روش آزمایش .............................................................................................................................
3-4- دستگاههای آنالیز استفاده شده در آزمایشات ....................................................................
3-4-1- دستگاه جذب اتمی .............................................................................................................
3-4-2- میکروسکوپ الکترونی روبشی .........................................................................................
3-4-3- طیف سنج پراش اشعه ایکس ...........................................................................................
فصل چهارم: بحث و نتیجهگیری
4-1- تاثیر pH .....................................................................................................................................
4-2- تاثیر شدت جریان تزریق ........................................................................................................
4-3- تاثیر شدت همزدن ...................................................................................................................
4-4- تاثیر غلظت واکنشگرها ...........................................................................................................
4-5- تاثیر غلظت اولیه کادمیوم ......................................................................................................
4-6- تاثیر دما ......................................................................................................................................
4-7- تاثیر جابجایی واکنشگرها .......................................................................................................
عنوان
4-8- تاثیر حضور و عدم حضور دانههای اولیه ..............................................................................
4-9- اثر افزایش کربنات آمونیوم به جای کربنات سدیم ...........................................................
4-10- اثر استفاده از پساب یک واحد صنعتی .............................................................................
4-11- تعیین مکانیسم همرسوبی ...................................................................................................
4-12- ضریب توزیع ...........................................................................................................................
4-13- سختی آب ...............................................................................................................................
4-14- حذف کادمیوم از نمونه واقعی ............................................................................................
4-15- عکسبرداری SEM ...............................................................................................................
4-16- آنالیز XRD ............................................................................................................................
4-17- درصد خطا آزمایشها ..........................................................................................................
فصل پنجم: نتیجهگیری و پیشنهادات
5-1- نتیجهگیری کلی .......................................................................................................................
5-2- پیشنهادات .................................................................................................................................
فهرست منابع و مآخذ
منابع فارسی ..........................................................................................................................................
منابع انگلیسی .......................................................................................................................................
منبع:
اسدی فرد، رضا. تیلکی، رضا. رنجبر، مهدی. دینی، مهدی. عرب، اصغر. قجاوند، مجید. کارگری، علیرضا و مرادی، امید (1385)." آشنایی با تجهیزات آزمایشگاهی فناوری نانو (اندازهگیری و تعیین مشخصات)". ویرایش چهارم، تهران: دبیرخانه ستاد ویژه توسعه فناوری نانو.
چالکش امیری، محمد (1389). "اصول تصفیه آب". ویرایش اول، چاپ هشتم، تهران اردکان دانش.
رحیمی آلاشتی، سپیده. بهمنیار محمد علی و قاجار سپانلو، مهدی (1390). "نقش لجن فاضلاب بر میزان pH، O.C و EC خاک وتجمع سرب و کادمیوم در خاک و گیاه کاهو و تربچه". مجله پژوهشهای حفاظت آب و خاک، ج 18، شماره سوم.
ماده 1 آیین نامه جلوگیری از آلودگی آب، مصوبه شماره 18241/ت 71 ه، هیأت وزیران، 1373.
موسسه استاندارد و تحقیقات صنعتی ایران، آب آشامیدنی – ویژگیهای فیزیکی و شیمیایی، کمیسیون فنی تدون استاندارد، شماره استاندارد 1053، تجدید نظر پنجم، 1388.
منابع انگلیسی
Abbasi, E. and Alamdari, A., 2007. Mixing effects on particle size distribution in semi-batch reactive crystallization of maneb. Journal of Chemical Engineering of Japan, 40(8): 636-644.
Amin, N., El-Ashtoukhy, E. and Abdelwahab, O., 2007. Rate of cadmium ions removal from dilute solutions by cementation on zinc using a rotating fixed bed reactor. Hydrometallurgy, 89(3): 224-232.
Anderson, N. and Rubin, A.J., 1981. Adsorption of inorganics at solid-liquid interfaces. Ann Arbor Science Publishers, Inc.
Asfari, F., Feyzbakhsh, A. and Heravi, N.E., 2009. Solvent extraction of cadmium (II) from sulfate medium by bis (2-ethylhexyl) phosphoric acid in toluene. International Journal of Chem. Tech. Research, 1(3): 420-425.
Bakhtiari, linda. (2012).”Experimental study of Arsenic removal from drinking water.” M. Sc. Thesis in chemical engineering, Shiraz University, January 2012.
Barbar, M. Mohamad. (2011). “Removal of lead from oil-field brine through coprecipitation process.” M. Sc. Thesis in chemical engineering, Shiraz University, Februray 2011.
Barreira, L.D. et al., 2009. Effect of pH on cadmium (II) removal from aqueous solution using titanosilicate ETS-4. Chemical Engineering Journal, 155(3): 728-735.
Bessbousse, H., Verchère, J.F. and Lebrun, L., 2012. Characterisation of metal-complexing membranes prepared by the semi-interpenetrating polymer networks technique. Application to the removal of heavy metal ions from aqueous solutions. Chemical Engineering Journal.
Bots, P., 2011. Experimental investigation of calcium carbonate mineralogy in past and future oceans, University of Leeds.
Boulkroune, N. and Meniai, A., 2012. Modeling Purification of Phosphoric Acid Contaminated with Cadmium by Liquid-liquid Extraction. Energy Procedia, 18: 1189-1198.
Brinkman, U.A.T., de Vries, G., Jochemsen, R. and de Jong, G.J., 1974. The use of aqueous thiocyanate solutions in liquid-liquid extraction and reversed-phase extraction chromatography. I. Journal of Chromatography A, 102(0): 309-317.
Camarinha, E.D. et al., 2009. Cadmium (II) removal from aqueous solution using microporous titanosilicate ETS-10. Chemical Engineering Journal, 155(1): 108-114.
Casas, I., Miralles, N., Sastre, A. and Aguilar, M., 1989. Extraction of cadmium (II) by mixtures of organophosphorus compounds. Polyhedron, 8(21): 2535-2541.
Chamjangali, M., Farooji, S.T. and Bahramian, B., 2010. Application of chloromethylated polystyrene functionalized with N, N-bis (naphthylideneimino) diethylenetriamine in an on-line preconcentration system for the determination of cadmium by FAAS. Journal of hazardous materials, 174(1): 843-850.
Chaney, R.L. et al., 2004. An improved understanding of soil Cd risk to humans and low cost methods to phytoextract Cd from contaminated soils to prevent soil Cd risks. BioMetals, 17(5): 549-553.
Citak, D., Tuzen, M. and Soylak, M., 2009. Simultaneous coprecipitation of lead, cobalt, copper, cadmium, iron and nickel in food samples with zirconium (IV) hydroxide prior to their flame atomic absorption spectrometric determination. Food and Chemical Toxicology, 47(9): 2302-2307.
Dieckmann, G. et al., 2010. Ikaite (CaCO3. 6H2O) discovered in Arctic sea ice. The Cryosphere, 4: 227-230.
Doner, G. and Ege, A., 2005. Determination of copper, cadmium and lead in seawater and mineral water by flame atomic absorption spectrometry after coprecipitation with aluminum hydroxide. Analytica Chimica Acta, 547(1): 14-17.
Duran, C. et al., 2011. Preconcentration of Cd (II) and Cu (II) ions by coprecipitation without any carrier element in some food and water samples. Microchemical Journal, 98(2): 317-322.
Elkady, M. et al., 2011. Nano-sulphonated poly (glycidyl methacrylate) cations exchanger for cadmium ions removal: Effects of operating parameters. Desalination, 279(1): 152-162.
Elyahyaoui, A. and Bouhlassa, S., 2001. Extraction of cadmium and iodocadmat species by di (2-ethylhexyl) phosphoric acid from perchloric and phosphoric media. Applied Radiation and Isotopes, 54(6): 921-926.
Ennaassia, E., El Kacemi, K., Kossir, A. and Cote, G., 2002. Study of the removal of Cd (II) from phosphoric acid solutions by precipitation of CdS with Na< sub> 2 S. Hydrometallurgy, 64(2): 101-109.
Fujino, O., Kumagai, T., Shigematsu, T. and Matsui, M., 1976. Coprecipitation of cadmium with calcite. Bulletin of the Institute for Chemical Research, Kyoto University, 54(5): 312-319.
Ghaedi, M., Niknam, K., Taheri, K., Hossainian, H. and Soylak, M., 2010. Flame atomic absorption spectrometric determination of copper, zinc and manganese after solid-phase extraction using 2, 6-dichlorophenyl-3, 3-bis (indolyl) methane loaded on Amberlite XAD-16. Food and Chemical Toxicology, 48(3): 891-897.
Jha, M.K., Kumar, V., Jeong, J. and Lee, J., 2011. Review on solvent extraction of cadmium from various solutions. Hydrometallurgy.
Jha, M.K., Kumar, V. and Singh, R., 2001. Review of hydrometallurgical recovery of zinc from industrial wastes. Resources, conservation and recycling, 33(1): 1-22.
Jha, M.K., Kumar, V. and Singh, R., 2002. Solvent extraction of zinc from chloride solutions. Solvent Extraction and Ion Exchange, 20(3): 389-405.
Karavasteva, M., 1997. The effect of certain surfactants on the cementation of cadmium by suspended zinc particles. Hydrometallurgy, 47(1): 91-98.
Katsuta, S., Tsuchiya, F. and Takeda, Y., 2000. Equilibrium studies on complexation in water and solvent extraction of zinc(II) and cadmium(II) with benzo-18-crown-6. Talanta, 51(4): 637-644.
Khosravi, J. and Alamdari, A., 2009. Copper removal from oil-field brine by coprecipitation. Journal of hazardous materials, 166(2): 695-700.
Kitano, Y., Kanamori, N. and Fujiyoshi, R., 1978a. Distribution of cadmium between calcium carbonate and solution (part 1)“Ca (HCO 3) 2+ Cd 2++ bipyridine→ carbonate” system. Geochem. J, 12: 137-145.
Kitano, Y., Kanamori, N. and Fujiyoshi, R., 1978b. Distribution of cadmium between calcium carbonate and solution. 2." Ca (HCO3) 2+ Cd2++ NaCl. RAR. carbonate" system. GEOCHEMICAL JOURNAL, 12(3): 147-151.
Kocaoba, S. and Akcin, G., 2005. Removal of chromium (III) and cadmium (II) from aqueous solutions. Desalination, 180(1): 151-156.
Kumagai, T., Fujino, O., Matsui, M. and Shigematsu, T., 1976. Coprecipitation of cadmium with aragonite. Bulletin of the Institute for Chemical Research, Kyoto University, 54(5): 320-329.
Lewis, A.E., 2010. Review of metal sulphide precipitation. Hydrometallurgy, 104(2): 222-234.
Mahmood, T. et al., 2011. Cation exchange removal of Cd from aqueous solution by NiO. Journal of Hazardous Materials, 185(2): 824-828.
Manahan, S.E., 2004. Environmental Chemistry, Eighth Edition. Taylor & Francis.
Matlock, M.M., Howerton, B.S., Henke, K.R. and Atwood, D.A., 2001. A pyridine-thiol ligand with multiple bonding sites for heavy metal precipitation. Journal of Hazardous Materials, 82(1): 55-63.
Mauchauffée, S., Meux, E. and Schneider, M., 2008. Selective precipitation of cadmium from nickel cadmium sulphate solutions using sodium decanoate. Separation and Purification Technology, 62(2): 394-400.
Mayergoyz, I.D. and Engdahl, G., 1999. Handbook of giant magnetostrictive materials. Academic press.
McClellan, B., Meredith, M., Parmelee, R. and Beck, J., 1974. Solvent extraction studies of chromium (III) with tri-n-octylamine. Analytical Chemistry, 46(2): 306-308.
Mellah, A. and Benachour, D., 2006. The solvent extraction of zinc and cadmium from phosphoric acid solution by di-2-ethyl hexyl phosphoric acid in kerosene diluent. Chemical Engineering and Processing: Process Intensification, 45(8): 684-690.
Mellah, A. and Benachour, D., 2007. The solvent extraction of zinc, cadmium and chromium from phosphoric acid solutions by tri-< i> n butyl phosphate in kerosene diluent. Separation and Purification Technology, 56(2): 220-224.
Mendham, J., 2006. Vogels textbook of quantitative chemical analysis. Pearson Education India.
Mendham, J., Denney, R., Barnes, J. and Thomas, M., Vogel’s Textbook of Quantitative Chemical Analysis, 2000. Prentice Hall, London, New York, Toronto.
Mendham, J., Denney, R., Barnes, J. and Thomas, M., 2000. Vogel’s Textbook of Quantitative Chemical Analysis. Prentice Hall, London, New York, Toronto.
Merian, E., 1991. Metals and their compounds in the environment: occurrence, analysis and biological relevance. VCH Verlagsgesellschaft mbH.
Mitchell, N., 2012. Numerical modelling of cooling crystallisation: process kinetics to optimisation.
Mohammad, A. and Shashi, B.V., 2001. Heavy Metals and Environment. New Age International Limited Publishers.
Moradkhani, D., Urbani, M., Cheng, C.Y., Askari, M. and Bastani, D., 2005. The separation of cadmium from zinc with a synergistic mixture of nonylsalicylic acid and triisobutylphosphine sulphide. Hydrometallurgy, 78(1): 129-136.
Mousavi, S. H. Zavar., Fazli, Mostafa and Bahmani, Akram., 2011. Removal of cadmium from aqueous solution by nano structured γ-Alumina. Journal of water and Wastewater. 4 (11): 9-18.
Muhammed, M., Valiente, M., Aguilar, M. and Masana, M., 1989. Separation of base divalent metals from chloride solutions by solvent extraction processes. Chem. Scripta, 29(2): 149-153.
Mullin, J.W., 2001. Crystallization. Butterworth-Heinemann.
Nagaosa, Y. and Binghua, Y., 1997. Extraction equilibria of some transition metal ions by bis (2-ethylhexyl) phosphinic acid. Talanta, 44(3): 327-337.
Nazari, K., Ghadiri, A. and Babaie, H., 2005. Elimination of cadmium from wet process phosphoric acid with Alamine 336. Minerals Engineering, 18(13): 1233-1238.
Nehrke, G., 2007. Calcite precipitation from aqueous solution: transformation from vaterite and role of solution stoichiometry, Universität Utrecht, Niederlande.
Nogueira, C.A. and Delmas, F., 1999. New flowsheet for the recovery of cadmium, cobalt and nickel from spent Ni–Cd batteries by solvent extraction. Hydrometallurgy, 52(3): 267-287.
Ouhenia, S., Chateigner, D., Belkhir, M., Guilmeau, E. and Krauss, C., 2008. Synthesis of calcium carbonate polymorphs in the presence of polyacrylic acid. Journal of Crystal Growth, 310(11): 2832-2841.
Parus, A., Wieszczycka, K. and Olszanowski, A., 2011. Solvent extraction of cadmium(II) from chloride solutions by pyridyl ketoximes. Hydrometallurgy, 105(3–4): 284-289.
Pourreza, N. and Ghanemi, K., 2010. Solid phase extraction of cadmium on 2-mercaptobenzothiazole loaded on sulfur powder in the medium of ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate and cold vapor generation–atomic absorption spectrometric determination. Journal of hazardous materials, 178(1): 566-571.
Preston, J., Patrick, J. and Steinbach, G., 1994. The selective solvent extraction of cadmium by mixtures of carboxylic acids and trialkylphosphine sulphides. Part 2. Practical applications in the separation of cadmium from zinc and nickel. Hydrometallurgy, 36(2): 143-160.
Preston, J.S. and du Preez, A.C., 1996. SYNERGISTIC EFFECTS IN SOLVENT-EXTRACTION SYSTEM BASED ON ALKYLSALICYLIC ACIDS. PART 2. EXTRACTION OF NICKEL, COBALT, CADMIUM AND ZINC IN THE PRESENCE OF SOME NEUTRAL N-, O-AND S-DONOR COMPOUNDS. Solvent Extraction and Ion Exchange, 14(2): 179-201.
Preston, J.S. and Preez, A.C.d., 1994. THE SOLVENT EXTRACTION OF CADMIUM AND ZINC BY MIXTURES OF CARBOXYLIC ACIDS AND ALKANETHIOLS. Solvent Extraction and Ion Exchange, 12(4): 667-685.
Ramachandra Reddy, B., Neela Priya, D. and Rajesh Kumar, J., 2004. Solvent extraction of cadmium (II) from sulphate solutions using TOPS 99, PC 88A, Cyanex 272 and their mixtures. Hydrometallurgy, 74(3–4): 277-283.
Rao, K., Mohapatra, M., Anand, S. and Venkateswarlu, P., 2011. Review on cadmium removal from aqueous solutions. International Journal of Engineering, Science and Technology, 2(7).
Reddy, B.R., Neela Priya, D., Venkateswara Rao, S. and Radhika, P., 2005. Solvent extraction and separation of Cd (II), Ni (II) and Co (II) from chloride leach liquors of spent Ni–Cd batteries using commercial organo-phosphorus extractants. Hydrometallurgy, 77(3): 253-261.
Reddy, B.R., Priya, D.N. and Park, K.H., 2006. Separation and recovery of cadmium (II), cobalt (II) and nickel (II) from sulphate leach liquors of spent Ni–Cd batteries using phosphorus based extractants. Separation and Purification Technology, 50(2): 161-166.
Rodrı́guez de San Miguel, E., Aguilar, J.C., Rodrı́guez, M.T.J. and de Gyves, J., 2000. Solvent extraction of Ga(III), Cd(II), Fe(III), Zn(II), Cu(II), and Pb(II) with ADOGEN 364 dissolved in kerosene from 1–4 mol dm−3 HCl media. Hydrometallurgy, 57(2): 151-165.
Saljoughi, E. and Mousavi, S.M., 2012. Preparation and characterization of novel polysulfone nanofiltration membranes for removal of cadmium from contaminated water. Separation and Purification Technology, 90: 22-30.
Sato, T., Adachi, K., Kato, T. and Nakamura, T., 1982. The extraction of divalent manganese, cobalt, copper, zinc, and cadmium from hydrochloric acid solutions by tri-n-octylamine. Separation Science and Technology, 17(13-14): 1565-1576.
Sato, T. and Nakamura, T., 1980. The stability constants of the aqueous chloro complexes of divalent zinc, cadmium and mercury determined by solvent extraction with tri-n-octylphosphine oxide. Hydrometallurgy, 6(1): 3-12.
Shawabkeh, R., Al-Harahsheh, A., Hami, M. and Khlaifat, A., 2004. Conversion of oil shale ash into zeolite for cadmium and lead removal from wastewater. Fuel, 83(7): 981-985.
Silva, E.L., Roldan, P.S. and Giné, M.F., 2009. Simultaneous preconcentration of copper, zinc, cadmium, and nickel in water samples by cloud point extraction using 4-(2-pyridylazo)-resorcinol and their determination by inductively coupled plasma optic emission spectrometry. Journal of hazardous materials, 171(1): 1133-1138.
Singh, D., Singh, O. and Tandon, S., 1978. Extraction Behavior of Zinc (II), Cadmium (II), Mercury (II), Indium (III), and Thallium (III) as Thiocyanates in High-Molecular-Weight Amines and Some Mutual Binary Separations. Separation Science and Technology, 13(7): 625-632.
Skoog, D., West, D. and Holler, F., 1996. Fundamentals of Analytical Chemistry, Thomson Learning. Inc, USA.
Soylak, M. and Aydin, A., 2011. Determination of some heavy metals in food and environmental samples by flame atomic absorption spectrometry after coprecipitation. Food and Chemical Toxicology, 49(6): 1242-1248.
Stenström, S. and Aly, G., 1985. Extraction of cadmium from phosphoric acid solutions with amines Part I. Extractant selection, stripping, scrubbing and effects of other components. Hydrometallurgy, 14(2): 231-255.
Summerfield, S. and Reid, H., 2010. Introduction to Atomic Spectrometry.
Taha, A. and Abd El-Ghani, S., 2004. Effect of surfactants on the cementation of cadmium. Journal of colloid and interface science, 280(1): 9-17.
Takeda, Y., 1984. The solvent extraction of metal ions by crown compounds. Host Guest Complex Chemistry III: 1-38.
Taylor, J., DeWoskin, R. and Ennever, F.K., 1999. Toxicological profile for cadmium. US Department of Health and Human Services, Agency for Toxic Substances and Disease Registry (ATSDR). Atlanta, GA, USA. ASIN: B002BRUYP6.
Verhaege, M., 1975. Influence of the chloride concentration on the distribution and separation of zinc and cadmium by means of solvent extraction with carboxylic acids. Hydrometallurgy, 1(1): 97-102.
Wang, F., Wang, L.J., Li, J.S., Sun, X.Y. and Han, W.Q., 2009. Adsorption behavior and mechanism of cadmium on strong-acid cation exchange resin. Transactions of Nonferrous Metals Society of China, 19(3): 740-744.
Wassink, B., Dreisinger, D. and Howard, J., 2000. Solvent extraction separation of zinc and cadmium from nickel and cobalt using Aliquat 336, a strong base anion exchanger, in the chloride and thiocyanate forms. Hydrometallurgy, 57(3): 235-252.
WHO, 2011. Cadmium in Drinking-water. Background document for development of WHO Guidelines for Drinking-water Quality.
Yaftian, M.R., Zamani, A.A., Parinejad, M. and Shams, E., 2005. Ion-pair extraction of cadmium complex anions from hydrochloric acid media using oxonium ion-dicyclohexyl-18-crown-6 complex. Separation and Purification Technology, 42(2): 175-180.
Younesi, S., Alimadadi, H., Alamdari, E.K. and Marashi, S., 2006. Kinetic mechanisms of cementation of cadmium ions by zinc powder from sulphate solutions. Hydrometallurgy, 84(3): 155-164.
Zhang, L., Zhao, Y.H. and Bai, R., 2011. Development of a multifunctional membrane for chromatic warning and enhanced adsorptive removal of heavy metal ions: Application to cadmium. Journal of Membrane Science, 379(1): 69-79