پایان نامه مطالعه آزمایشگاهی تولید اکسید آهن در مقیاس ریز ساختاری با استفاده از روش ترسیب با ضد حلال فوق بحرانی

فهرست:

2

فصل اول: مقدمه.

2

1-1- پیشگفتار ..................................................................................................................................................

3

1-2- نانو فناوری و کاربرد آن در صنعت نفت....................................................................................... ....

4

1-3- نانو فناوری و سیمان چاه های نفتی............................................................................................. .....

4

1-4- معرفی برخی از نانو افزودنی های مورد استفاده در سیمان................................................... ....

8

1-5- تعریف سیال فوق بحرانی................................................................................................................. ....

10

1-6- مزایای استخراج بوسیله سیال فوق بحرانی................................................................................. ....

11

1-7- کاربردهای فناوری فوق بحرانی....................................................................................................... ....

12

1-8- کاربرد فرآیندهای فوق بحرانی در تولید ریز ذرات.................................................................... ....

14

1-8-1- فرآیند RESS................................................................................................................................. ....

15

1-8-2- فرآیند PGSS................................................................................................................................. ....

16

1-8-3- فرآیند SAS ، GASوPCA....................................................................................................... ....

22

فصل دوم: مروری بر تحقیقات گذشته

37

فصل سوم: پایلوت آزمایش .

37

3-1- مبانی طراحی و مشخصات پایلوت استخراج فوق بحرانی ........................................................

38

3-2- بررسی اجزای اصلی تشکیل دهنده پایلوت فوق بحرانی...........................................................

38

3-2-1- تأمین فشار آزمایش........................................................................................................................

39

3-2-2- تأمین دمای آزمایش.......................................................................................................................

39

3-2-3- ظرف اصلی آزمایش........................................................................................................................

39

3-2-4- فیلتر فلزی.........................................................................................................................................

39

3-3- طراحی دستگاه آزمایشگاهی فوق بحرانی.....................................................................................

40

3-3-1- ظرف اصلی ......................................................................................................................................

42

3-3-2- فیلتر فلزی.........................................................................................................................................

43

3-3-3- ظرف مایع سازی( یخچال) گاز دی اکسید­کربن.....................................................................         

44

3-3-4- پمپ فشار قوی................................................................................................................................

45

3-3-5- سیستم‎ گرمایش و سرمایش(مخزن آب)..................................................................................

46

3-3-6- سیستم‎های کنترل.........................................................................................................................

47

3-3-7- لوازم جانبی.......................................................................................................................................

50

3-4- انجام تست هیدرولیک دستگاه.........................................................................................................

52

فصل چهارم: روش انجام آزمایش­ها.....................................................................................

52

4 4-1- مواد استفاده شده .......................................................................................................................... .

53

4-2- روش انجام آزمایش............................................................................................................................. ..

54

4-3- آنالیز محصولات................................................................................................................................... ...

54

4-3-1- آنالیز میکروسکوپ الکترون روبشی ......................................................................................... ...

55

4-3-2- نرم افزار image analysis3.2 (SIS).................................................................................. .

58

فصل پنجم: نتایج .......

58

5-1- بحث و نتیجه­گیری ........................................................................................................................... ....

62

5-2- اثر غلظت............................................................................................................................................... ....

63

5-3- اثر فشار.................................................................................................................................................. ....

65

5-4- اثر دما.................................................................................................................................................... .....

66

5-5- اثر دبی دی اکسید­کربن................................................................................................................... .....

67

5-6- نتیجه­گیری........................................................................................................................................... ....

69

منابع................................................................................................................................................................... ....

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